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Anna Williams was born in Haywood County TN. She is the daughter of Jerry Williams (1848-1923) and Sallie Miller. Her siblings were Nellie Williams, Liza Jane Williams, Melissa Williams, Emmaline Williams, Mary Helen Williams, Lucy Harriett Williams, Sam Williams, Eugene Williams, Jerry Williams, Roger Williams, Jasper Williams.
Anna Williams's husband is not known. They had two known children named Sam Williams and Susie Williams.