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Charlie Mottley is the son of Jim T. Mottley and Emma Mae Kneeland. His siblings were Dorothy Mottley, Earnest Mottley, Regina Mottley, Cleo Mottley, Viola Mottley, Jerry Mottley, Morris Mottley, Leshell Mottley, Alfred Mottley, Karen Mottley, Angela Mottley, Mary Mottley, Agnettia Mottley, Jim Mottley.
Charlie Mottley's wife is not known. They had six known children named Veronica Mottley, Charlie , Jr. Mottley, Cherise Mottley, Lydia Mottley, Valaria Mottley, and Donna Mottley.